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A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures) [1] [2] is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
Solids can be classified according to the nature of the bonding between their atomic or molecular components. The traditional classification distinguishes four kinds of bonding: [1] Covalent bonding, which forms network covalent solids (sometimes called simply "covalent solids") Ionic bonding, which forms ionic solids
This page was last edited on 20 July 2010, at 03:13 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
The inert-pair effect is the tendency of the two electrons in the outermost atomic s-orbital to remain unshared in compounds of post-transition metals.The term inert-pair effect is often used in relation to the increasing stability of oxidation states that are two less than the group valency for the heavier elements of groups 13, 14, 15 and 16.
Metallic glasses, for example, are typically well described by the dense random packing of hard spheres, whereas covalent systems, such as silicate glasses, have sparsely packed, strongly bound, tetrahedral network structures. These very different structures result in materials with very different physical properties and applications.
However, they are distinguished from thermosets by the incorporation of dynamic covalent chemistry into the polymer network. When a stimulus (for example heat, light, pH, ...) is applied to the material, these dynamic bonds become active and can be broken or exchanged with other pending functional groups , allowing the polymer network to change ...
Crystalline solids generally consist of an ordered array of interconnected atoms, generated by repetition of a unit cell in three dimensions, and are of two extreme types—ionic crystals, and covalent crystals. Others are intermediate: partly ionic and partly covalent.