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The radius ratio rule defines a critical radius ratio for different crystal structures, based on their coordination geometry. [1] The idea is that the anions and cations can be treated as incompressible spheres, meaning the crystal structure can be seen as a kind of unequal sphere packing .
An octahedron may then form with a radius ratio greater than or equal to 0.414, but as the ratio rises above 0.732, a cubic geometry becomes more stable. This explains why Na + in NaCl with a radius ratio of 0.55 has octahedral coordination, whereas Cs + in CsCl with a radius ratio of 0.93 has cubic coordination.
For all these radius ratios a compact packing is known that achieves the maximum possible packing fraction (above that of uniformly-sized discs) for mixtures of discs with that radius ratio. [9] All nine have ratio-specific packings denser than the uniform hexagonal packing, as do some radius ratios without compact packings.
Template: Atomic radius. ... Download as PDF; Printable version; In other projects ... This page was last edited on 31 May 2023, at 19:41 (UTC).
Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice .
The radius of the first arc must be chosen large enough to cause all successive arcs to end on the correct side of the next crossing point; however, all sufficiently-large radii work. For two lines, this forms a circle; for three lines on the sides of an equilateral triangle, with the minimum possible radius, it forms a Reuleaux triangle, and ...
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
A power diagram is a type of Voronoi diagram defined from a set of circles using the power distance; it can also be thought of as a weighted Voronoi diagram in which a weight defined from the radius of each circle is added to the squared Euclidean distance from the circle's center. [15]
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