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1-nitropropane is produced industrially by the reaction of propane and nitric acid. This reaction forms four nitroalkanes: nitromethane , nitroethane , 1-nitropropane, and 2-nitropropane . 1-nitropropane is also a byproduct of the process for making 2-nitropropane, which is done by vapour phase nitration of propane.
This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, such as CH 3 CH 2 CH 2 O., which arise via homolysis of the corresponding nitrite ester. These alkoxy radicals are susceptible to C—C fragmentation reactions, which ...
Aliphatic nitro compounds can be synthesized by various methods; notable examples include: Free radical nitration of alkanes . [ 4 ] The reaction produces fragments from the parent alkane, creating a diverse mixture of products; for instance, nitromethane , nitroethane , 1-nitropropane , and 2-nitropropane are produced by treating propane with ...
A classic example of NGP is the reaction of a sulfur or nitrogen mustard with a nucleophile, the rate of reaction is much higher for the sulfur mustard and a nucleophile than it would be for a primary or secondary alkyl chloride without a heteroatom. [4] Ph−S−CH 2 −CH 2 −Cl reacts with water 600 times faster than CH 3 −CH 2 −CH 2 ...
Nitropropane may refer to: 1-Nitropropane; 2-Nitropropane This page was last edited on 16 May 2022, at 02:06 (UTC). Text is available under the Creative Commons ...
1,4-Dioxane (/ d aɪ ˈ ɒ k s eɪ n /) is a heterocyclic organic compound, classified as an ether. It is a colorless liquid with a faint sweet odor similar to that of diethyl ether . The compound is often called simply dioxane because the other dioxane isomers ( 1,2- and 1,3- ) are rarely encountered.
With water and a protic acid such as sulfuric acid as the reaction medium and formaldehyde the reaction product is a 1,3-diol (3). When water is absent, the cationic intermediate loses a proton to give an allylic alcohol (4). With an excess of formaldehyde and a low reaction temperature the reaction product is a dioxane (5).
If column dimensions Length×diameter×film are divided by 2 and gas velocity is doubled by using H2 in place of Helium, the hold times must be divided by 4 and the ramps must be multiplied by 4 to keep the same index and the same retention temperature for the same compound analyzed. Method translation rules are incorporated in some ...