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Formic acid (from Latin formica 'ant'), systematically named methanoic acid, is the simplest carboxylic acid, and has the chemical formula HCOOH and structure H−C(=O)−O−H. It is an important intermediate in chemical synthesis and occurs naturally, most notably in some ants. Esters, salts and the anion derived from formic acid are called ...
Formate salts have the formula M(O 2 CH)(H 2 O) x. Such salts are prone to decarboxylation. For example, hydrated nickel formate decarboxylates at about 200 °C with reduction of the Ni 2+ to finely powdered nickel metal: Ni(HCO 2) 2 (H 2 O) 2 → Ni + 2 CO 2 + 2 H 2 O + H 2. Such fine powders are useful as hydrogenation catalysts. [1]
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
The general formula of a carboxylic acid is often written as R−COOH or R−CO 2 H, sometimes as R−C(O)OH with R referring to an organyl group (e.g., alkyl, alkenyl, aryl), or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids.
In the laboratory, methyl formate can be produced by the condensation reaction of methanol and formic acid, as follows: . HCOOH + CH 3 OH → HCOOCH 3 + H 2 O. Industrial methyl formate, however, is usually produced by the combination of methanol and carbon monoxide (carbonylation) in the presence of a strong base, such as sodium methoxide: [4]
Structural formula pentanoic acid: valeric acid valerianic acid butane-1-carboxylic acid: CH 3 (CH 2) 3 COOH 3-methylbutanoic acid: isovaleric acid isopentanoic acid delphinic acid β-methylbutiric acid 3-methylbutiric acid (CH 3) 2 CHCH 2 COOH 2-methylbutanoic acid: 2-methylbutiric acid: CH 3 CH 2 CH(CH 3)COOH 2,2-dimethylpropanoic acid ...
Sodium formate is used in several fabric dyeing and printing processes. It is also used as a buffering agent for strong mineral acids to increase their pH, as a food additive (E237), and as a de-icing agent.
Lone pairs (shown as pairs of dots) in the Lewis structure of hydroxide. In chemistry, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bond [1] and is sometimes called an unshared pair or non-bonding pair. Lone pairs are found in the outermost electron shell of atoms.