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Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. [1] As a mineral the ammonium nickel salt, (NH 4) 2 Ni(SO 4) 2 · 6 H 2 O, can be called nickelboussingaultite. [2]
Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. [37] As a mineral the ammonium nickel salt, (NH 4) 2 Ni(SO 4) 2 · 6 H 2 O, can be called nickelboussingaultite. [38]
However in other organic solvents, or molten salts the tetrachloronickelate ion can form. Nickel can be separated from such a solution in water or methanol, by partitioning it into a cyclohexane solution of amines. [2] Organic ammonium salts of the type (R 3 NH) 2 [NiCl 4] are often thermochromic (R = Me, Et, Pr). Near room temperature, these ...
The nickel organic acid salts are organic acid salts of nickel. In many of these the ionised organic acid acts as a ligand. Nickel acetate has the formula (CH 3 COO) 2 Ni·4H 2 O. It has monodentate acetate and hydrogen bonding. A dihydrate also exists. Nickel acetate is used to seal anodised aluminium. [1]
Other examples include the vanadous Tutton salt (NH 4) 2 V(SO 4) 2 (H 2 O) 6 and the chromous Tutton salt (NH 4) 2 Cr(SO 4) 2 (H 2 O) 6. [5] In solids and solutions, the M' 2+ ion exists as a metal aquo complex [M'(H 2 O) 6] 2+. Related to the Tutton's salts are the alums, which are also double salts but with the formula MM'(SO 4) 2 (H 2 O) 12 ...
The first periodatonickalates discovered were sodium nickel periodate (NaNiIO 6 ·0.5H 2 O) and potassium nickel periodate (KNiIO 6 ·0.5H 2 O). P. P. Ray and B. Sarma obtained these dark purple double salts in 1949, mixing nickel sulfate with potassium or sodium periodate and (as oxidant) a boiling aqueous solution of an alkali persulfate ...
Nickel(II) chloride (or just nickel chloride) is the chemical compound NiCl 2. The anhydrous salt is yellow, but the more familiar hydrate NiCl 2 ·6H 2 O is green. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form ...
It is the chloride salt of the metal ammine complex [Ni(NH 3) 6] 2+. The cation features six ammonia (called ammines in coordination chemistry) ligands attached to the nickel (II) ion. [ 1 ]