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2 FeSO 4 Fe 2 O 3 + SO 2 + SO 3. Like other iron(II) salts, iron(II) sulfate is a reducing agent. For example, it reduces nitric acid to nitrogen monoxide and chlorine to chloride: 6 FeSO 4 + 3 H 2 SO 4 + 2 HNO 3 → 3 Fe 2 (SO 4) 3 + 4 H 2 O + 2 NO 6 FeSO 4 + 3 Cl 2 → 2 Fe 2 (SO 4) 3 + 2 FeCl 3
The various crystalline forms of Fe 2 (SO 4) 3 (H 2 O) n are well-defined, often by X-ray crystallography. The nature of the aqueous solutions is often less certain, but aquo-hydroxo complexes such as [Fe(H 2 O) 6] 3+ and [Fe(H 2 O) 5 (OH)] 2+ are often assumed. [4] Regardless, all such solids and solutions feature ferric ions, each with five ...
Ammonium ferric citrate (also known as ferric ammonium citrate or ammoniacal ferrous citrate) has the formula [NH 4]y[Fe x (C 6 H 4 O 7)].The iron in this compound is trivalent.All three carboxyl groups and the central hydroxyl group of citric acid are deprotonated.
The formation of Fe(III)-EDTA (FeY) − can be described as follows: FeSO 4 ∙7H 2 O + K 2 H 2 Y + 1/4 O 2 → K[FeY(H 2 O)]. H 2 O + KHSO 4 + 5.5 H 2 O (1) [8]. Iron chelate has also been used as a bait in the chemical control of slugs, snails and slaters in agriculture in Australia and New Zealand.
Greigite, Fe 3 S 4 (cubic) Pyrrhotite, Fe 1−x S (where x = 0 to 0.2) (monoclinic or hexagonal) Troilite, FeS, the endmember of pyrrhotite (hexagonal)
Thiolate-ligated oxoiron(IV) is formed by the oxidation of a precursor, [Fe II (TMCS)](PF 6) (TMCS = 1-mercaptoethyl-4,8,11-trimethyl-1,4,8,11-tetraza cyclotetradecane), and 3-5 equivalents of H 2 O 2 at -60 ˚C in methanol. The iron(IV) compound is deep blue in color and shows intense absorption features at 460 nm, 570 nm, 850 nm, and 1050 nm.
Hydroxylammonium sulfate is prepared industrially via the Raschig hydroxylamine process, which involves the reduction of nitrite with bisulfite.This initially gives hydroxylamine disulfonate, which is hydrolysed to hydroxylammonium sulfate: [2] It can also be obtained by the acid-base reaction of hydroxylamine with sulfuric acid:
Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN) 6] 4−. In its hydrous form, Na 4 Fe(CN) 6 · H 2 O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ...