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Nitric acid reacts with most metals, but the details depend on the concentration of the acid and the nature of the metal. Dilute nitric acid behaves as a typical acid in its reaction with most metals. Magnesium, manganese, and zinc liberate H 2: Mg + 2 HNO 3 → Mg(NO 3) 2 + H 2 Mn + 2 HNO 3 → Mn(NO 3) 2 + H 2 Zn + 2 HNO 3 → Zn(NO 3) 2 + H 2
Another method involves the reaction of urea, nitric acid and sulfuric acid: [54] 2 (NH 2) 2 CO + 2 HNO 3 + H 2 SO 4 → 2 N 2 O + 2 CO 2 + (NH 4) 2 SO 4 + 2 H 2 O. Direct oxidation of ammonia with a manganese dioxide-bismuth oxide catalyst has been reported: [55] cf. Ostwald process. 2 NH 3 + 2 O 2 → N 2 O + 3 H 2 O
A base other than ammonia must be added before the acid dinitramide decomposes. The final product is obtained by fractional crystallization. Another synthesis known as the urethane synthesis method requires four synthesis steps and results in a yield of up to 60%. [12] Ethyl carbamate is nitrated with nitric acid:
Solutions of dinitrogen pentoxide in nitric acid can be seen as nitric acid with more than 100% concentration. The phase diagram of the system H 2 O − N 2 O 5 shows the well-known negative azeotrope at 60% N 2 O 5 (that is, 70% HNO 3), a positive azeotrope at 85.7% N 2 O 5 (100% HNO 3), and another negative one at 87.5% N 2 O 5 ("102% HNO 3 ...
Aqua regia (/ ˈ r eɪ ɡ i ə, ˈ r iː dʒ i ə /; from Latin, "regal water" or "royal water") is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. [ b ] Aqua regia is a fuming liquid.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
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Nitrous acid is also highly unstable, tending to disproportionate: 3 HNO 2 (aq) ⇌ H 3 O + + NO − 3 + 2 NO. This reaction is slow at 0 °C. [2] Addition of acid to a solution of a nitrite in the presence of a reducing agent, such as iron(II), is a way to make nitric oxide (NO) in the laboratory.