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In pure water at the negatively charged cathode, a reduction reaction takes place, with electrons (e −) from the cathode being given to hydrogen cations to form hydrogen gas. At the positively charged anode, an oxidation reaction occurs, generating oxygen gas and giving electrons to the anode to complete the circuit.
Cathode reaction: O 2 + 4e − → 2O 2− Overall cell reaction: 2H 2 + O 2 → 2H 2 O. SOFC systems can run on fuels other than pure hydrogen gas. However, since hydrogen is necessary for the reactions listed above, the fuel selected must contain hydrogen atoms. For the fuel cell to operate, the fuel must be converted into pure hydrogen gas.
A solid oxide electrolyzer cell (SOEC) is a solid oxide fuel cell that runs in regenerative mode to achieve the electrolysis of water (and/or carbon dioxide) [ 1 ] by using a solid oxide, or ceramic, electrolyte to produce hydrogen gas [ 2 ] (and/or carbon monoxide) and oxygen. The production of pure hydrogen is compelling because it is a clean ...
The reaction at the anode results in chlorine gas from chlorine ions: 2 Cl − → Cl 2 + 2 e −. The reaction at the cathode results in hydrogen gas and hydroxide ions: 2 H 2 O + 2 e − → H 2 + 2 OH −. Without a partition between the electrodes, the OH − ions produced at the cathode are free to diffuse throughout the electrolyte to the ...
Electrolyte. An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. [1][2][3] This includes most soluble salts, acids, and bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout ...
The hydrogen ions permeate across the electrolyte to the cathode, while the electrons flow through an external circuit and produce electric power. Oxygen, usually in the form of air, is supplied to the cathode and combines with the electrons and the hydrogen ions to produce water. The reactions at the electrodes are as follows: Anode reaction:
The electrolysis occurs in a specially designed reactor which allows the separation of the cathodic and anodic solutions. In this process, hydrogen gas and hydroxide ions can be produced at the cathode, leading to an alkaline solution that consists essentially of sodium hydroxide. At the anode, chloride ions can be oxidized to elemental ...
As already noted, water, particularly when ions are added (saltwater or acidic water), can be electrolyzed (subjected to electrolysis). When driven by an external source of voltage, hydrogen (H +) ions flow to the cathode to combine with electrons to produce hydrogen gas in a reduction reaction. Likewise, hydroxide (OH −