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Alkenes can be made from alcohols by dehydration. This conversion, among others, is used in converting biomass to liquid fuels. [2] The conversion of ethanol to ethylene is a fundamental example: [3] [4] CH 3 CH 2 OH → H 2 C=CH 2 + H 2 O. The reaction is accelerated by acid catalysts such as sulfuric acid and certain zeolites.
Alcohols have a long history of myriad uses. For simple mono-alcohols, which is the focus on this article, the following are most important industrial alcohols: [25] methanol, mainly for the production of formaldehyde and as a fuel additive; ethanol, mainly for alcoholic beverages, fuel additive, solvent, and to sterilize hospital instruments. [26]
The most pervasive is the application of non-toxic cosolvents with water to produce formulations that can dissolve hydrophobic molecules while maintaining cohesion with biological systems. Common cosolvents for this purpose are ethanol, propylene glycol, glycerine, glycofural, and polyethylene glycols. [ 7 ]
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate ...
The unimolecular nucleophilic substitution (S N 1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses two properties—"S N " stands for " nucleophilic substitution ", and the "1" says that the rate-determining step is unimolecular .
Building on the reactivity of the triphenylphosphine ligand, the structure of ligands used for the Tsuji–Trost reaction quickly became more complex. Today, these ligands may contain phosphorus, sulfur, nitrogen or some combination of these elements, but most studies have concentrated on the mono- and diphosphine ligands.
Ammonolysis refers to solvolysis by ammonia, but can also describe nucleophilic attack by ammonia more generally. Ammonia boils at −33 °C, and, as such, is rarely used as a solvent in its pure form. It is, however, readily miscible with water, and is commonly used in the form of a saturated aqueous solution. For this reason, ammonolysis may ...
Hydrolysis (/ h aɪ ˈ d r ɒ l ɪ s ɪ s /; from Ancient Greek hydro- 'water' and lysis 'to unbind') is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. [1]