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Zinc nitrate is an inorganic chemical compound with the formula Zn(NO 3) 2. This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate Zn(NO 3) 2 ·6H 2 O. It is soluble in both water and alcohol.
Color code: red = O, green = Zn. Zinc carbonate adopts the same structure as calcite (calcium carbonate). [7] Zinc is octahedral and each carbonate is bonded to six Zn centers such that oxygen atoms are three-coordinate.
Zn 2+ is a class A acceptor in the classification of Ahrland, Chatt and Davies, [16] and so forms stronger complexes with the first-row donor atoms oxygen or nitrogen than with second-row sulfur or phosphorus. In terms of HSAB theory Zn 2+ is a hard acid. In aqueous solution an octahedral complex, [Zn(H 2 O) 6] 2+ is the predominant species. [17]
2, Zn 3 P 2, Zn 3 As 2 and Zn 3 Sb 2), [65] [66] the peroxide (ZnO 2), the hydride (ZnH 2), and the carbide (ZnC 2) are also known. [67] Of the four halides, ZnF 2 has the most ionic character, while the others (ZnCl 2, ZnBr 2, and ZnI 2) have relatively low melting points and are considered to have more covalent character. [68] In weak basic ...
The method is illustrated by the route to β-Cu(NO 3) 2: Cu + 2 N 2 O 4 → Cu(NO 3) 2 + 2 NO. Many metals, metal halides, and metal carbonyls undergo similar reactions, but the product formulas can be deceptive. For example from chromium one obtains Cr(NO 3) 3 (N 2 O 4) 2, which was shown to be the salt (NO +) 2 [Cr(NO 3) 5] 2-. [15]
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (Zn CO 3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion.
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Zn 2+ + 2 OH − → Zn(OH) 2. The initial colorless solution contains the zincate ion: Zn(OH) 2 + 2 OH − → Zn(OH) 4 2−. Zinc hydroxide will dissolve because the ion is normally surrounded by water ligands; when excess sodium hydroxide is added to the solution the hydroxide ions will reduce the complex to a −2 charge and make it soluble.