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mno 2 + so 2 + h 2 o → mnso 4 (h 2 o) It can also be made by mixing potassium permanganate with sodium hydrogen sulfate and hydrogen peroxide . Manganese sulfate is a by-product of various industrially significant oxidations that use manganese dioxide, including the manufacture of hydroquinone and anisaldehyde .
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO·Mn 2 O 3. Mn 3 O 4 is found in nature as the mineral hausmannite.
It may refer more specifically to the following manganese minerals: Birnessite, (Na,Ca) 0.5 (Mn IV,Mn III) 2 O 4 · 1.5 H 2 O; Buserite, MnO 2 ·nH 2 O; Hausmannite, Mn II Mn III 2 O 4; Manganite, Mn III O(OH)
The most stable are 53 Mn with a half-life of 3.7 million years, 54 Mn with a half-life of 312.2 days, and 52 Mn with a half-life of 5.591 days. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less than one minute.
This vocalic w generally represented /uː/, [3] [4] as in wss ("use"). [5] However at that time the form w was still sometimes used to represent a digraph uu (see W), not as a separate letter. In modern Welsh, "W" is simply a single letter which often represents a vowel sound. Thus words borrowed from Welsh may use w this way, such as:
MnCO 3 → MnO + CO 2. This calcining process is conducted anaerobically, lest Mn 2 O 3 form. An alternative route, most interest for demonstration purposes, is the "oxalate method". Also applicable to the synthesis of ferrous oxide and stannous oxide, it entails heating in an oxygen-free atmosphere (often CO 2), hydrated manganese(II) oxalate: [9]
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The most important is Mn 3 N 2, which catalyzes nitrogen fixation and is a high-temperature antiferromagnet. The others are Mn 6 N 5–6, Mn 4 N, [1] [2] and Mn 2 N. [3] The compounds generally form as surface layer during combustion of manganese metal in nitrogen or ammonia gas, and homogenous samples can be difficult to obtain.