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Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. [1] There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process).
The Lindemann criterion states that melting occurs because of "vibrational instability", e.g. crystals melt; when the average amplitude of thermal vibrations of atoms is relatively high compared with interatomic distances, e.g. <δu 2 > 1/2 > δ L R s, where δu is the atomic displacement, the Lindemann parameter δ L ≈ 0.20...0.25 and R s is ...
If the vapor then condenses to a liquid on a surface, then the vapor's latent energy absorbed during evaporation is released as the liquid's sensible heat onto the surface. The large value of the enthalpy of condensation of water vapor is the reason that steam is a far more effective heating medium than boiling water, and is more hazardous.
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
where P 1, P 2 are the vapor pressures at temperatures T 1, T 2 respectively, ΔH vap is the enthalpy of vaporization, and R is the universal gas constant. The rate of evaporation in an open system is related to the vapor pressure found in a closed system. If a liquid is heated, when the vapor pressure reaches the ambient pressure the liquid ...
The solidus temperature specifies the temperature below which a material is completely solid, [2] and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium. Liquidus and solidus are mostly used for impure substances (mixtures) such as glasses , metal alloys , ceramics , rocks , and minerals .
Volatility can also describe the tendency of a vapor to condense into a liquid or solid; less volatile substances will more readily condense from a vapor than highly volatile ones. [1] Differences in volatility can be observed by comparing how fast substances within a group evaporate (or sublimate in the case of solids) when exposed to the ...
Ideally, the melt rate stays constant throughout the process cycle, but monitoring and control of the vacuum arc remelting process is not simple. [5] This is because there is a complex heat transfer occurring involving conduction, radiation, convection within the liquid metal, and advection caused by the Lorentz force .
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