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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer.Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
The undissolved waste, bauxite tailings, after the aluminium compounds are extracted contains iron oxides, silica, calcia, titania and some un-reacted alumina. After separation of the residue by filtering, pure gibbsite is precipitated when the liquid is cooled, and then seeded with fine-grained aluminium hydroxide.
Bauxite is blended for uniform composition and then is ground. The resulting slurry is mixed with a hot solution of sodium hydroxide; the mixture is then treated in a digester vessel at a pressure well above atmospheric, dissolving the aluminium hydroxide in bauxite while converting impurities into relatively insoluble compounds: [141]
The liquid aluminium is removed from the cell via a siphon every 1 to 3 days in order to avoid having to use extremely high temperature valves and pumps. Alumina is added to the cells as the aluminum is removed. Collected aluminium from different cells in a factory is finally melted together to ensure uniform product and made into metal sheets.
The Hall-Héroult electrolysis process is the major production route for primary aluminium. An electrolytic cell is made of a steel shell with a series of insulating linings of refractory materials. The cell consists of a brick-lined outer steel shell as a container and support. Inside the shell, cathode blocks are cemented together by ramming ...
Bauxite was discovered in 1821 by Pierre Berthier who named it after a village named Les Beaux where he found it. [6] To obtain the alumina from the bauxite ore, a process was developed that used acid to dissolve aluminium but resulted in a product that contained large amounts of iron and titanium dissolved within which were difficult to remove. [6]
A metamorphic rock called emery that is mostly made of corundum which is an aluminum oxide. This is an example of an aluminum deposit. Aluminum is the third most abundant element in the lithosphere at 82,000 ppm. It occurs in low levels, 0.9 ppm, in humans. [1] Aluminum is known to be an ecotoxicant and expected to be a health risk to people.
The first stage is the calcination of the bauxite at 1200 °C with sodium carbonate and coke. The alumina is converted in sodium aluminate. Iron oxide remains unchanged and silica forms a polysilicate. In the second stage sodium hydroxide solution is added, which dissolves the sodium aluminate, leaving the impurities as a solid residue. The ...