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Sodium perchlorate is an inorganic compound with the chemical formula Na Cl O 4. It consists of sodium cations Na + and perchlorate anions ClO − 4 . It is a white crystalline, hygroscopic solid that is highly soluble in water and ethanol .
Perchlorate salts are typically manufactured through the process of electrolysis, which involves oxidizing aqueous solutions of corresponding chlorates.This technique is commonly employed in the production of sodium perchlorate, which finds widespread use as a key ingredient in rocket fuel. [5]
Perchloric acid is produced industrially by two routes. The traditional method exploits the high aqueous solubility of sodium perchlorate (209 g/100 ml of water at room temperature). Treatment of such solutions with hydrochloric acid gives perchloric acid, precipitating solid sodium chloride: NaClO 4 + HCl → NaCl + HClO 4
Sodium chlorate is an inorganic compound with the chemical formula Na ClO 3.It is a white crystalline powder that is readily soluble in water. It is hygroscopic.It decomposes above 300 °C to release oxygen [4] and leaves sodium chloride.
Potassium and lithium chlorate, and sodium, potassium and lithium perchlorates can also be used in oxygen candles. In the Vika oxygen generator used on some spacecraft, lithium perchlorate is the source of oxygen. At 400 °C (750 °F), it releases 60% of its weight as oxygen: [9] LiClO 4 → LiCl + 2 O 2
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Potassium perchlorate in crystal form. Potassium perchlorate is prepared industrially by treating an aqueous solution of sodium perchlorate with potassium chloride.This single precipitation reaction exploits the low solubility of KClO 4, which is about 1/100 as much as the solubility of NaClO 4 (209.6 g/100 mL at 25 °C).
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