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Ruthenium, like the other platinum group metals, is obtained commercially as a by-product from processing of nickel, copper, and platinum metal ore. During electrorefining of copper and nickel, noble metals such as silver, gold, and the platinum group metals precipitate as anode mud , the feedstock for the extraction.
The properties of ruthenium and osmium compounds are often similar. The +2, +3, and +4 states are the most common. The +2, +3, and +4 states are the most common. The most prevalent precursor is ruthenium trichloride , a red solid that is poorly defined chemically but versatile synthetically.
The hapticity of the hexamethylbenzene ligand in Ru(C 6 Me 6) 2 depends on the oxidation state of the metal centre: [14] The compound Ru is capable of dimerizing norbornadiene: Norbornadiene dimerization. Multinuclear organo-ruthenium complexes have been investigated for anti-cancer properties.
The platinum-group metals (PGMs), also known as the platinoids, platinides, platidises, platinum group, platinum metals, platinum family or platinum-group elements (PGEs), are six noble, precious metallic elements clustered together in the periodic table. These elements are all transition metals in the d-block (groups 8, 9, and 10, periods 5 ...
The Creutz–Taube ion. The Creutz–Taube ion is the metal complex with the formula {[Ru(NH 3) 5] 2 (C 4 H 4 N 2)} 5+.This cationic species has been heavily studied in an effort to understand the intimate details of inner sphere electron transfer, that is, how electrons move from one metal complex to another.
With its similar properties to and lower cost than rhodium, electric contacts are a major use of ruthenium. The ruthenium plate is applied to the electrical contact and electrode base metal by electroplating or sputtering. Osmium is a hard but brittle metal that remains lustrous even at high temperatures. It has a very low compressibility.
Ruthenium(IV) oxide is the inorganic compound with the formula Ru O 2. This black solid is the most common oxide of ruthenium . It is widely used as an electrocatalyst for producing chlorine, chlorine oxides, and O 2 . [ 1 ]
The refractory metals show a wide variety of chemical properties because they are members of three distinct groups in the periodic table. They are easily oxidized, but this reaction is slowed down in the bulk metal by the formation of stable oxide layers on the surface (passivation). Especially the oxide of rhenium is more volatile than the ...