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The profile for same reaction but with a catalyst is also shown. Figure 13: An energy profile diagram demonstrating the effect of a catalyst for the generic exothermic reaction of X + Y →Z. The catalyst offers an alternate reaction pathway (shown in red) where the rate determining step has a smaller ΔG≠.
In thermochemistry, an exothermic reaction is a "reaction for which the overall standard enthalpy change ΔH⚬ is negative." [ 1 ] [ 2 ] Exothermic reactions usually release heat . The term is often confused with exergonic reaction , which IUPAC defines as "... a reaction for which the overall standard Gibbs energy change Δ G ⚬ is negative."
Schematic potential energy diagram showing the effect of a catalyst in an endothermic chemical reaction. The presence of a catalyst opens a different reaction pathway (in red) with lower activation energy. The final result and the overall thermodynamics are the same.
The Boudouard reaction to form carbon dioxide and carbon is exothermic at all temperatures. However, the standard enthalpy of the Boudouard reaction becomes less negative with increasing temperature, [2] as shown to the side. While the formation enthalpy of CO 2 is higher than that of CO, the formation entropy is much lower.
In an adiabatic system (i.e. a system that does not exchange heat with the surroundings), an otherwise exothermic process results in an increase in temperature of the system. [11] In exothermic chemical reactions, the heat that is released by the reaction takes the form of electromagnetic energy or kinetic energy of molecules. [12]
An aldol condensation is a condensation reaction in organic chemistry in which two carbonyl moieties (of aldehydes or ketones) react to form a β-hydroxyaldehyde or β-hydroxyketone (an aldol reaction), and this is then followed by dehydration to give a conjugated enone.
The behavior of the catalyst is also a consideration. Particularly in high-temperature petrochemical processes, catalysts are deactivated by processes such as sintering , coking , and poisoning . A common example of a catalytic reactor is the catalytic converter that processes toxic components of automobile exhausts.
The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.