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  2. Point groups in three dimensions - Wikipedia

    en.wikipedia.org/wiki/Point_groups_in_three...

    However, there are three more infinite series of symmetry groups with this abstract group type: C nv of order 2n, the symmetry group of a regular n-sided pyramid; D nd of order 4n, the symmetry group of a regular n-sided antiprism; D nh of order 4n for odd n. For n = 1 we get D 2, already covered above, so n ≥ 3. Note the following property:

  3. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    In a symmetry group, the group elements are the symmetry operations (not the symmetry elements), and the binary combination consists of applying first one symmetry operation and then the other. An example is the sequence of a C 4 rotation about the z-axis and a reflection in the xy-plane, denoted σ(xy) C 4 .

  4. Symmetry group - Wikipedia

    en.wikipedia.org/wiki/Symmetry_group

    A frequent notation for the symmetry group of an object X is G = Sym(X). For an object in a metric space, its symmetries form a subgroup of the isometry group of the ambient space. This article mainly considers symmetry groups in Euclidean geometry, but the concept may also be studied for more general types of geometric structure.

  5. Octahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Octahedral_molecular_geometry

    In chemistry, octahedral molecular geometry, also called square bipyramidal, [1] describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa.

  6. List of spherical symmetry groups - Wikipedia

    en.wikipedia.org/wiki/List_of_spherical_symmetry...

    Finite spherical symmetry groups are also called point groups in three dimensions. There are five fundamental symmetry classes which have triangular fundamental domains: dihedral, cyclic, tetrahedral, octahedral, and icosahedral symmetry. This article lists the groups by Schoenflies notation, Coxeter notation, [1] orbifold notation, [2] and order.

  7. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− ⁠ 1 / 3 ⁠ ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .

  8. Square pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_pyramidal_molecular...

    The point group symmetry involved is of type C 4v. The geometry is common for certain main group compounds that have a stereochemically-active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN) 5] 3−. [1]

  9. Trigonal planar molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_planar_molecular...

    In chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane. [1] In an ideal trigonal planar species, all three ligands are identical and all bond angles are 120°.