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In chemistry, an acyl group is a moiety derived by the removal of one or more hydroxyl groups from an oxoacid, [1] including inorganic acids. It contains a double-bonded oxygen atom and an organyl group ( R−C=O ) or hydrogen in the case of formyl group ( H−C=O ).
A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H 2n−1. [2] Typically an alkyl is a part of a larger molecule. In structural formulae, the symbol R is used to designate a generic (unspecified) alkyl group. The smallest alkyl group is methyl, with the formula −CH 3 ...
An acyl halide (also known as an acid halide) is a chemical compound derived from an oxoacid [1] by replacing a hydroxyl group (−OH) with a halide group (−X, where X is a halogen). [ 2 ] In organic chemistry , the term typically refers to acyl halides of carboxylic acids ( −C(=O)OH ), which contain a −C(=O)X functional group consisting ...
In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group ( −CH 3 ) that is single-bonded to a carbonyl ( C=O ), making it an acyl group . The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter R ) of the ...
The insertion of carbon monoxide into a metal-carbon bond to form an acyl group is the basis of carbonylation reactions, which provides many commercially useful products. Mechanistic. Studies reveal that the alkyl group migrates intramolecularly to an adjacent CO ligand. [2] [3] CO Insertion reaction pathway for an octahedral complex
Note that a phenyl group is not the same as a benzyl group, the latter consisting of a phenyl group attached to a methyl group and a molecular formula of C 6 H 5 CH 2 −. [2] Phenol (or hydroxybenzene) To name compounds containing phenyl groups, the phenyl group can be taken to be the parent hydrocarbon and be represented by the suffix ...
In chemistry, acylation is a broad class of chemical reactions in which an acyl group (R−C=O) is added to a substrate. The compound providing the acyl group is called the acylating agent. The substrate to be acylated and the product include the following: alcohols, esters; amines, amides; arenes or alkenes, [1] ketones
The "tail" groups are also not simply n-alkyl groups, but highly methylated chains made up of saturated isoprenoid units (e.g. phytanyl). [15] Among different groups of archaea, diverse modifications on the basic archaeol backbone have emerged. The two (usually C 20) tails can be linked together, forming a macrocyclic lipid. [15]