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For example, when a path for conduction or radiation is made available, heat always flows spontaneously from a hotter to a colder body. Such phenomena are accounted for in terms of entropy change . [ 12 ] [ 13 ] A heat pump can reverse this heat flow, but the reversal process and the original process, both cause entropy production, thereby ...
At the heat source of a system of natural circulation, the heated fluid becomes lighter than the fluid surrounding it, and thus rises. At the heat sink, the nearby fluid becomes denser as it cools, and is drawn downward by gravity. Together, these effects create a flow of fluid from the heat source to the heat sink and back again.
A prime example of this irreversibility is the transfer of heat by conduction or radiation. It was known long before the discovery of the notion of entropy that when two bodies, initially of different temperatures, come into direct thermal connection, then heat immediately and spontaneously flows from the hotter body to the colder one.
A traditional version of the second law of thermodynamics states: Heat does not spontaneously flow from a colder body to a hotter body. The second law refers to a system of matter and radiation, initially with inhomogeneities in temperature, pressure, chemical potential, and other intensive properties , that are due to internal 'constraints ...
In many real-life applications (e.g. heat losses at solar central receivers or cooling of photovoltaic panels), natural and forced convection occur at the same time (mixed convection). [4] Internal and external flow can also classify convection. Internal flow occurs when a fluid is enclosed by a solid boundary such as when flowing through a pipe.
Such spontaneous heat transfer always occurs from a region of high temperature to another region of lower temperature, as described in the second law of thermodynamics. Heat convection occurs when the bulk flow of a fluid (gas or liquid) carries its heat through the fluid. All convective processes also move heat partly by diffusion, as well.
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
The rate of heat flow is the amount of heat that is transferred per unit of time in some material, usually measured in watts (joules per second). Heat is the flow of thermal energy driven by thermal non-equilibrium, so the term 'heat flow' is a redundancy (i.e. a pleonasm). Heat must not be confused with stored thermal energy, and moving a hot ...