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The earliest military, industrial, and agricultural applications of nitrogen compounds used saltpetre (sodium nitrate or potassium nitrate), most notably in gunpowder, and later as fertiliser. In 1910, Lord Rayleigh discovered that an electrical discharge in nitrogen gas produced "active nitrogen", a monatomic allotrope of nitrogen. [20]
Structure of a noble-gas atom caged within a buckminsterfullerene (C 60) molecule. Noble gases can also form endohedral fullerene compounds where the noble gas atom is trapped inside a fullerene molecule. In 1993, it was discovered that when C 60 is exposed to a pressure of around 3 bar of He or Ne, the complexes He@C 60 and Ne@C 60 are formed ...
Nitrogen bonds to almost all the elements in the periodic table except the first three noble gases, helium, neon, and argon, and some of the very short-lived elements after bismuth, creating an immense variety of binary compounds with varying properties and applications. [3]
The noble gases have also been referred to as inert gases, but this label is deprecated as many noble gas compounds are now known. [6] Rare gases is another term that was used, [ 7 ] but this is also inaccurate because argon forms a fairly considerable part (0.94% by volume, 1.3% by mass) of the Earth's atmosphere due to decay of radioactive ...
Nevertheless, nitrogen gas does react with the alkali metal lithium to form compound lithium nitride (Li 3 N), even under ordinary conditions. Under high pressures and temperatures and with the right catalysts, nitrogen becomes more reactive; the Haber process uses such conditions to produce ammonia from atmospheric nitrogen. [3]
For example, N 2, the diatomic form of nitrogen, is used as an inert gas in situations where using argon or another noble gas would be too expensive. Formation of multiple bonds is facilitated by their five valence electrons, as the octet rule permits a pnictogen to accept three electrons on covalent bonding.
The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. [1] [2] Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N 2, 1% Ar in air) [3] and low relative cost.
A gas regulator attached to a nitrogen cylinder. Industrial gases are the gaseous materials that are manufactured for use in industry.The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other gases and mixtures are also available in gas cylinders.