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Nitrous acid (molecular formula H N O 2) is a weak and monoprotic acid known only in solution, in the gas phase, and in the form of nitrite (NO − 2) salts. [3] It was discovered by Carl Wilhelm Scheele, who called it "phlogisticated acid of niter". Nitrous acid is used to make diazonium salts from amines.
Nitric acid is an inorganic compound with the formula H N O 3.It is a highly corrosive mineral acid. [6] The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into oxides of nitrogen.
Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others, [4] is a chemical compound, an oxide of nitrogen with the formula N 2 O. At room temperature, it is a colourless non-flammable gas, and has a slightly sweet scent and taste. [4]
In organic chemistry, alkyl nitrites are esters of nitrous acid and contain the nitrosoxy functional group. Nitro compounds contain the C–NO 2 group. Nitrites have the general formula RONO, where R is an aryl or alkyl group. Amyl nitrite and other alkyl nitrites have a vasodilating action and must be handled in the laboratory with caution ...
The method exploits the reactivity of nitrous acid derived from acidification of nitrite. Nitrous acid selectively reacts with aromatic amines to give diazonium salts, which in turn couple with a second reagent to give the azo dye. The detection limit is 0.02 to 2 μM. [3] Such methods have been highly adapted to biological samples. [4]
Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour.
Ammonium nitrite is a chemical compound with the chemical formula [NH 4]NO 2. It is the ammonium salt of nitrous acid. It is composed of ammonium cations [NH 4] + and nitrite anions NO − 2. It is not used in pure isolated form since it is highly unstable and decomposes into water and nitrogen, even at room temperature.
There are two possible structures of hyponitrous acid, trans and cis.trans-Hyponitrous acid forms white crystals that are explosive when dry.In aqueous solution, it is a weak acid (pK a1 = 7.21, pK a2 = 11.54), [2] and decomposes to nitrous oxide and water with a half life of 16 days at 25 °C at pH 1–3: