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The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
With a constant pressure, the voltage needed to cause an arc reduced as the gap size was reduced but only to a point. As the gap was reduced further, the voltage required to cause an arc began to rise and again exceeded its original value. For a given gas, the voltage is a function only of the product of the pressure and gap length.
In fluid dynamics, the pressure coefficient is a dimensionless number which describes the relative pressures throughout a flow field. The pressure coefficient is used in aerodynamics and hydrodynamics. Every point in a fluid flow field has its own unique pressure coefficient, C p.
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
VLE of the mixture of chloroform and methanol plus NRTL fit and extrapolation to different pressures. The non-random two-liquid model [1] (abbreviated NRTL model) is an activity coefficient model introduced by Renon and Prausnitz in 1968 that correlates the activity coefficients of a compound with its mole fractions in the liquid phase concerned.
Solar radiation pressure on objects near the Earth may be calculated using the Sun's irradiance at 1 AU, known as the solar constant, or G SC, whose value is set at 1361 W/m 2 as of 2011. [17] All stars have a spectral energy distribution that depends on their surface temperature.