Search results
Results from the WOW.Com Content Network
tert-Butyl chloride is the organochloride with the formula (CH 3) 3 CCl. It is a colorless, flammable liquid. It is sparingly soluble in water, with a tendency to undergo hydrolysis to the corresponding tert-butyl alcohol. It is produced industrially as a precursor to other organic compounds. [1]
Tetrabutylammonium chloride is the organic compound with the formula [(CH 3 CH 2 CH 2 CH 2) 4 N] + Cl −, often abbreviated as [Bu 4 N]Cl, where Bu stands for n-butyl. A white water-soluble solid, it is a quaternary ammonium salt of chloride. It is a precursor to other tetrabutylammonium salts.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
As such it is more bulky that trimethylsilyl chloride. It is a colorless or white solid that is soluble in many organic solvents but reacts with water and alcohols. The compound is used to protect alcohols in organic synthesis. [1] tert-Butyldimethylsilyl chloride reacts with alcohols in the presence of base to give tert-butyldimethylsilyl ...
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
It was originally prepared by the oxidation of pinacolone with chromic acid [2] and by the hydrolysis of tert-butyl cyanide. [3] Convenient laboratory routes proceed via carbonation of the Grignard reagent formed from tert-butyl chloride [4] and by oxidation of pinacolone. [5] Pinacol rearrangement
The search engine that helps you find exactly what you're looking for. Find the most relevant information, video, images, and answers from all across the Web.
tert-Butyl chloride (2-chloro-2-methylpropane) This page was last edited on 25 November 2020, at 11:39 (UTC). Text is available under the Creative Commons Attribution ...