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The Schlosser base (or Lochmann-Schlosser base), the combination of n-butyllithium and potassium tert-butoxide, is commonly cited as a superbase. n -Butyllithium and potassium tert -butoxide form a mixed aggregate of greater reactivity than either component reagent.
This toxic compound is formed when powdered osmium is exposed to air. It is a very volatile, water-soluble, pale yellow, crystalline solid with a strong smell. Osmium powder has the characteristic smell of osmium tetroxide. [31] Osmium tetroxide forms red osmates OsO 4 (OH) 2− 2 upon reaction with a base.
HSAB is an acronym for "hard and soft (Lewis) acids and bases".HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species.
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The higher the proton affinity, the stronger the base and the weaker the conjugate acid in the gas phase.The (reportedly) strongest known base is the ortho-diethynylbenzene dianion (E pa = 1843 kJ/mol), [3] followed by the methanide anion (E pa = 1743 kJ/mol) and the hydride ion (E pa = 1675 kJ/mol), [4] making methane the weakest proton acid [5] in the gas phase, followed by dihydrogen.
A Lewis base is also a Brønsted–Lowry base, but a Lewis acid does not need to be a Brønsted–Lowry acid. The classification into hard and soft acids and bases ( HSAB theory ) followed in 1963. The strength of Lewis acid-base interactions, as measured by the standard enthalpy of formation of an adduct can be predicted by the Drago–Wayland ...
Mahogany Rush was a Canadian rock band led by guitarist Frank Marino.Formed in Montreal, Quebec in 1969, the band had its peak of popularity in the 1970s, playing venues as large as California Jam II.
Owner Steve Cohen — who also had a strong year off the diamond — is a man who can afford such luxuries as a $765 million ballplayer. The price is eye-popping. It also doesn’t really matter.