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The chromate coating acts as paint does, protecting the zinc from white corrosion, thus making the part considerably more durable, depending on the chromate layer's thickness. [8] [9] [10] The protective effect of chromate coatings on zinc is indicated by color, progressing from clear/blue to yellow, gold, olive drab and black.
Zinc chromate, Zn Cr O 4, is a chemical compound, a salt containing the chromate anion, appearing as odorless yellow powder or yellow-green crystals, but, when used for coatings, pigments are often added. [2] [3] [4] It is used industrially in chromate conversion coatings, having been developed by the Ford Motor Company in the 1920s. [5]
The Cronak process is a conventional chromate conversion coating process developed in 1933 by The New Jersey Zinc Company. [1] It involves immersing a zinc or zinc-plated article for 5 to 15 seconds in a chromate solution, typically prepared from sodium dichromate and sulfuric acid. [2]
Chromate and dichromate salts of heavy metals, lanthanides and alkaline earth metals are only very slightly soluble in water and are thus used as pigments. The lead-containing pigment chrome yellow was used for a very long time before environmental regulations discouraged its use. [ 7 ]
Such zinc electroplating or zinc alloy electroplating maintains a dominant position among other electroplating process options, based upon electroplated tonnage per annum. According to the International Zinc Association, more than 5 million tons are used yearly for both hot-dip galvanization and electroplating. [ 1 ]
Brown or black can be used as a base color for copper patina. If the amount of chlorides decreases the color will be more bluish-green, if carbonate decreases, more yellow-green. [27] Black for copper. Solution of sodium polysulfide 2.5%, items must be submerged in the solution after color developing, wash, dry and wax or varnish colored object ...
Mechanical plating, also known as peen plating, mechanical deposition, or impact plating, is a plating process that imparts the coating by cold welding fine metal particles to a workpiece. Mechanical galvanization is the same process, but applies to coatings that are thicker than 0.001 in (0.025 mm). [ 1 ]
Immersion zinc plating is an electroless (non-electrolytic) coating process that deposits a thin layer of zinc on a less electronegative metal, by immersion in a solution containing a zinc or zincate ions, Zn(OH) 2− 4. A typical use is plating aluminum with zinc prior to electrolytic or electroless nickel plating.