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Chlorides, particularly calcium chloride, have been used to shorten the setting time of concrete. [5] However, calcium chloride and (to a lesser extent) sodium chloride have been shown to leach calcium hydroxide and cause chemical changes in Portland cement, leading to loss of strength, [6] as well as attacking the steel reinforcement present ...
The attack arises from soils containing SO2−4 ions, such as MgSO 4 or Na 2 SO 4 soluble and hygroscopic salts. The tricalcium aluminate (C 3 A) hydrates first interact with sulfate ions to form ettringite (AFt). Ettringite crystallizes into small acicular needles slowly growing in the concrete pores. Once the pores are completely filled ...
Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. The effect of sulfuric acid on concrete ...
The alkali–silica reaction (ASR), also commonly known as concrete cancer, [3] is a deleterious internal swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous (i.e., non-crystalline) silica found in many common aggregates, given sufficient moisture.
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
Insulating concrete form or insulated concrete form (ICF) is a system of formwork for reinforced concrete usually made with a rigid thermal insulation that stays in place as a permanent interior and exterior substrate for walls, floors, and roofs. The forms are interlocking modular units that are dry-stacked (without mortar) and filled with ...
Leaching is the process of a solute becoming detached or extracted from its carrier substance by way of a solvent. [1] Leaching is a naturally occurring process which scientists have adapted for a variety of applications with a variety of methods. Specific extraction methods depend on the soluble characteristics relative to the sorbent material ...
Calthemite straw stalactite (right side) is bent due to direction of prevailing air movement during periods of its growth. Calthemite is a secondary deposit, derived from concrete, lime, mortar or other calcareous material outside the cave environment. [1][2] Calthemites grow on or under man-made structures and mimic the shapes and forms of ...