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Although the bond in a compound like X+Y- may be considered to be 100% ionic, it will always have some degree of covalent character. When two oppositely charged ions (X+ and Y-) approach each other, the cation attracts electrons in the outermost shell of the anion but repels the positively charged nucleus.
Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, [1] and is the primary interaction occurring in ionic compounds. It is one of the main types of bonding, along with covalent bonding and metallic bonding. Ions ...
Rather, bond types are interconnected and different compounds have varying degrees of different bonding character (for example, covalent bonds with significant ionic character are called polar covalent bonds). Six years later, in 1947, Ketelaar developed van Arkel's idea by adding more compounds and placing bonds on different sides of the triangle.
As noted above, covalent and ionic bonds form a continuum between shared and transferred electrons; covalent and weak bonds form a continuum between shared and unshared electrons. In addition, molecules can be polar, or have polar groups, and the resulting regions of positive and negative charge can interact to produce electrostatic bonding ...
In organic chemistry, covalent bonding is much more common than ionic bonding. Covalent bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center four-electron bonds. [2] [3] The term covalent bond dates from 1939 ...
Ionic bonding is a type of electrostatic interaction between atoms that have a large electronegativity difference. There is no precise value that distinguishes ionic from covalent bonding, but an electronegativity difference of over 1.7 is likely to be ionic while a difference of less than 1.7 is likely to be covalent. [21]
The circumstances under which a compound will have ionic or covalent character can typically be understood using Fajans' rules, which use only charges and the sizes of each ion. According to these rules, compounds with the most ionic character will have large positive ions with a low charge, bonded to a small negative ion with a high charge. [25]
The classical model identifies three main types of chemical bonds — ionic, covalent, and metallic — distinguished by the degree of charge separation between participating atoms. [3] The characteristics of the bond formed can be predicted by the properties of constituent atoms, namely electronegativity.