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  2. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    the simple first-order rate law described in introductory textbooks. Under these conditions, the concentration of the nucleophile does not affect the rate of the reaction, and changing the nucleophile (e.g. from H 2 O to MeOH) does not affect the reaction rate, though the product is, of course, different. In this regime, the first step ...

  3. SNi - Wikipedia

    en.wikipedia.org/wiki/SNi

    With standard S N 1 reaction conditions the reaction outcome is retention via a competing S N i mechanism and not racemization and with pyridine added the result is again inversion. [5] [3] S N i reaction mechanism Sn1 occurs in tertiary carbon while Sn2 occurs in primary carbon

  4. Hammond's postulate - Wikipedia

    en.wikipedia.org/wiki/Hammond's_postulate

    An E1 reaction consists of a unimolecular elimination, where the rate determining step of the mechanism depends on the removal of a single molecular species. This is a two-step mechanism. The more stable the carbocation intermediate is, the faster the reaction will proceed, favoring the products.

  5. Nucleophilic substitution - Wikipedia

    en.wikipedia.org/wiki/Nucleophilic_substitution

    In S N 2 reactions, there are a few conditions that affect the rate of the reaction. First of all, the 2 in S N 2 implies that there are two concentrations of substances that affect the rate of reaction: substrate (Sub) and nucleophile. The rate equation for this reaction would be Rate=k[Sub][Nuc].

  6. Reaction rate - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate

    Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]

  7. Today’s NYT ‘Strands’ Hints, Spangram and Answers for ...

    www.aol.com/today-nyt-strands-hints-spangram...

    According to the New York Times, here's exactly how to play Strands: Find theme words to fill the board. Theme words stay highlighted in blue when found.

  8. Iconic Riviera CC in evacuation zone for Pacific Palisades ...

    www.aol.com/iconic-riviera-cc-evacuation-zone...

    The iconic Riviera Country Club is being threatened while in the mandatory evacuation zone for the Pacific Palisades fire northwest of Los Angeles.

  9. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...