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Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of free electrons among a structure of positively charged ions .
Metallic solids have, by definition, no band gap at the Fermi level and hence are conducting. Solids with purely metallic bonding are characteristically ductile and, in their pure forms, have low strength; melting points can [inconsistent] be very low (e.g., Mercury melts at 234 K (−39 °C)). These properties are consequences of the non ...
The halides of low-valent early metals often are clusters with extensive M-M bonding. The situation contrasts with the higher halides of these metals and virtually all halides of the late transition metals, where metal-halide bonding is replete. Transition metal halide clusters are prevalent for the heavier metals: Zr, Hf, Nb, Ta, Mo, W, and Re.
An example of a metal–metal bond is found in dimanganese decacarbonyl, Mn 2 (CO) 10. As confirmed by X-ray crystallography, a pair of Mn(CO) 5 units are linked by a bond between the Mn atoms. The Mn-Mn distance (290 pm) is short. [3] Mn 2 (CO) 10 is a simple and clear case of a metal-metal bond because no other atoms tie the two Mn atoms ...
A less often mentioned type of bonding is metallic bonding. In this type of bonding, each atom in a metal donates one or more electrons to a "sea" of electrons that reside between many metal atoms. In this sea, each electron is free (by virtue of its wave nature) to be associated with a great many atoms at once. The bond results because the ...
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
In chemistry, a metallophilic interaction is defined as a type of non-covalent attraction between heavy metal atoms. The atoms are often within Van der Waals distance of each other and are about as strong as hydrogen bonds. [1] The effect can be intramolecular or intermolecular.
In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. [1] The ligand may be atomic or polyatomic. Virtually all complex organic compounds can serve as bridging ligands, so the term is usually restricted to small ligands such as pseudohalides or to ligands that are specifically designed to ...