Search results
Results from the WOW.Com Content Network
They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are dimensionless. [1] According to an IUPAC definition, [2] for a reaction with a single rate-determining step, the charge transfer coefficient for a cathodic reaction (the cathodic transfer coefficient, α c) is defined as:
This is known as the charge transfer rate. The second is the rate at which reactants are provided, and products removed, from the electrode region by various processes including diffusion, migration, and convection. The latter is known as the mass-transfer rate [Note 1]. These two rates determine the concentrations of the reactants and products ...
Continuous charge distribution. The volume charge density ρ is the amount of charge per unit volume (cube), surface charge density σ is amount per unit surface area (circle) with outward unit normal nĚ‚, d is the dipole moment between two point charges, the volume density of these is the polarization density P.
The weak mixing angle or Weinberg angle [2] is a parameter in the Weinberg–Salam theory of the electroweak interaction, part of the Standard Model of particle physics, and is usually denoted as θ W. It is the angle by which spontaneous symmetry breaking rotates the original W 0 and B 0 vector boson plane, producing as a result the Z 0
Position vectors r and r′ used in the calculation. Retarded time t r or t′ is calculated with a "speed-distance-time" calculation for EM fields.. If the EM field is radiated at position vector r′ (within the source charge distribution), and an observer at position r measures the EM field at time t, the time delay for the field to travel from the charge distribution to the observer is |r ...
This equation is characteristic of incoherent hopping transport, which takes place at low concentrations, where the limiting factor is the exponential decay of hopping probability with inter-site distance. [4] Sometimes this relation is expressed for conductivity, rather than mobility:
Without the contribution of the second term, the Hamiltonian resolves to the tight binding formula from regular band theory. Including the second term yields a realistic model that also predicts a transition from conductor to insulator as the ratio of interaction to hopping, U / t {\displaystyle U/t} , is varied.
The practical importance of high (i.e. close to 1) transference numbers of the charge-shuttling ion (i.e. Li+ in lithium-ion batteries) is related to the fact, that in single-ion devices (such as lithium-ion batteries) electrolytes with the transfer number of the ion near 1, concentration gradients do not develop. A constant electrolyte ...