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In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. [1] A simple example of this concept is that the empirical formula of sulfur monoxide, or SO, is simply SO, as is the empirical formula of disulfur dioxide, S 2 O 2.
An example of the difference is the empirical formula for glucose, which is CH 2 O (ratio 1:2:1), while its molecular formula is C 6 H 12 O 6 (number of atoms 6:12:6). For water, both formulae are H 2 O. A molecular formula provides more information about a molecule than its empirical formula, but is more difficult to establish.
In most cases the formula representing a formula unit will also be an empirical formula, such as calcium carbonate (CaCO 3) or sodium chloride (NaCl), but it is not always the case. For example, the ionic compounds potassium persulfate ( K 2 S 2 O 8 ), mercury(I) nitrate Hg 2 (NO 3 ) 2 , and sodium peroxide Na 2 O 2 , have empirical formulas of ...
Chemical formula Synonyms CAS number CAgO carbonylsilver: CCl 2 F 2: dichlorodifluoromethane freon-12: 75-71-8 CCl 4: carbon tetrachloride tetrachloromethane: 56-23-5 C(CN) 4: tetracyanomethane: 24331-09-7 CFCl 3: trichlorofluoromethane freon-11: 75-69-4 CFCl 2 CF 2 Cl: chlorotrifluoromethane freon-13: 75-72-9 CHCl 3: chloroform ...
The empirical formula is often the same as the molecular formula but not always. For example, the molecule acetylene has molecular formula C 2 H 2, but the simplest integer ratio of elements is CH. The molecular mass can be calculated from the chemical formula and is expressed in conventional atomic mass units equal to 1/12 of the mass of a ...
[100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion). To obtain the empirical formula from these names, the stoichiometry can be deduced from the charges on the ions, and the requirement of overall charge neutrality. [102]
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
Such compounds follow the law of multiple proportion. An example is the iron oxide wüstite, which can contain between 0.83 and 0.95 iron atoms for every oxygen atom, and thus contain anywhere between 23% and 25% oxygen by mass. The ideal formula is FeO, but it is about Fe 0.95 O due to crystallographic vacancies. In general, Proust's ...