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A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
The temperature of a muscle has a significant effect on the velocity and power of the muscle contraction, with performance generally declining with decreasing temperatures and increasing with rising temperatures. The Q 10 coefficient represents the degree of temperature dependence a muscle exhibits as measured by contraction rates. [2]
The second derivative essentially locates the intersection of tangents to the temperature curve immediately pre- and post- the breakpoint. Thermistors respond quickly to small changes in temperature such as temperature gradients in the mixed titration solution, and thus the signal can exhibit a small amount of noise.
Thermophoresis, the movement of the molecule in the temperature gradient, depends on three parameters that typically change upon interaction. Thus, the overall MST signal is plotted against the ligand concentration to obtain a dose-response curve, from which the binding affinity can be deduced.
The principle of time-temperature superposition requires the assumption of thermorheologically simple behavior (all curves have the same characteristic time variation law with temperature). From an initial spectral window [ ω 1 , ω 2 ] and a series of isotherms in this window, we can calculate the master curves of a material which extends ...
The result of a DSC experiment is a curve of heat flux versus temperature or versus time. There are two different conventions: exothermic reactions in the sample shown with a positive or negative peak, depending on the kind of technology used in the experiment. This curve can be used to calculate enthalpies of transitions. This is done by ...
Differential thermal analysis (DTA) is a thermoanalytic technique that is similar to differential scanning calorimetry.In DTA, the material under study and an inert reference are made to undergo identical thermal cycles, (i.e., same cooling or heating programme) while recording any temperature difference between sample and reference. [1]