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Acetone is produced directly or indirectly from propene. Approximately 83% of acetone is produced via the cumene process ; [ 24 ] as a result, acetone production is tied to phenol production. In the cumene process, benzene is alkylated with propylene to produce cumene , which is oxidized by air to produce phenol and acetone:
This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent conditions. This is apparent in the ΔE a, ΔΔG ‡ activation. On the right is an S N 2 reaction coordinate diagram. Note the decreased ΔG ‡ activation for the non-polar-solvent reaction ...
It is responsible for why water is a liquid at room temperature and not a gas (given water's low molecular weight). Most commonly, the strength of hydrogen bonds lies between 0–4 kcal/mol, but can sometimes be as strong as 40 kcal/mol [ 3 ] In solvents such as chloroform or carbon tetrachloride one observes e.g. for the interaction between ...
The carbonyl group is polar because the electronegativity of the oxygen is greater than that for carbon. Thus, ketones are nucleophilic at oxygen and electrophilic at carbon. Because the carbonyl group interacts with water by hydrogen bonding, ketones are typically more soluble in water than the related methylene compounds. Ketones are hydrogen ...
Nonpolar molecules stay together in water because it is energetically more favorable for the water molecules to hydrogen bond to each other than to engage in van der Waals interactions with non-polar molecules. An example of an ionic solute is table salt; the sodium chloride, NaCl, separates into Na + cations and Cl −
In the gas phase the dipole moment is ≈ 1.86 debye (D), [11] whereas liquid water (≈ 2.95 D) [12] and ice (≈ 3.09 D) [13] are higher due to differing hydrogen-bonded environments. Other examples include sugars (like sucrose ), which have many polar oxygen–hydrogen (−OH) groups and are overall highly polar.
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Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner.