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Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate [9]), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO 3. It is a salt composed of a sodium cation (Na +) and a bicarbonate anion (HCO 3 −). Sodium bicarbonate is a white solid that is crystalline but often appears as a
As calculated by the Henderson–Hasselbalch equation, in order to maintain a normal pH of 7.4 in the blood (whereby the pK a of carbonic acid is 6.1 at physiological temperature), a 20:1 ratio of bicarbonate to carbonic acid must constantly be maintained; this homeostasis is mainly mediated by pH sensors in the medulla oblongata of the brain ...
Bicarbonate is the dominant form of dissolved inorganic carbon in sea water, [9] and in most fresh waters. As such it is an important sink in the carbon cycle . Some plants like Chara utilize carbonate and produce calcium carbonate (CaCO 3 ) as result of biological metabolism.
The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts: + +---(IV)
This equation is demonstrated in the image below: Here, one molecule of water acts as an acid, donating an H + and forming the conjugate base, OH −, and a second molecule of water acts as a base, accepting the H + ion and forming the conjugate acid, H 3 O +. As an example of water acting as an acid, consider an aqueous solution of pyridine, C ...
It can substitute for baking soda (sodium bicarbonate) for those with a low-sodium diet, [4] and it is an ingredient in low-sodium baking powders. [5] [6] As an inexpensive, nontoxic base, it is widely used in diverse application to regulate pH or as a reagent. Examples include as buffering agent in medications, an additive in winemaking.
It dissolves in water to give a mildly alkaline solution. It is insoluble in acetone and alcohols . Ammonium bicarbonate decomposes above about 36 °C into ammonia , carbon dioxide , and water in an endothermic process and so causes a drop in the temperature of the water:
It can be formed through the reaction of dilute solutions of carbonic acid (such as seltzer water) and magnesium hydroxide (milk of magnesia). It can be prepared through the synthesis of magnesium acetate and sodium bicarbonate: Mg(CH 3 COO) 2 + 2 NaHCO 3 → Mg(HCO 3) 2 + 2 CH 3 COONa. Magnesium bicarbonate exists only in aqueous solution.