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  2. tert-Butyl bromide - Wikipedia

    en.wikipedia.org/wiki/Tert-butyl_bromide

    tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.

  3. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    An example of a reaction taking place with an S N 1 reaction mechanism is the hydrolysis of tert-butyl bromide forming tert-butanol: This S N 1 reaction takes place in three steps: Formation of a tert-butyl carbocation by separation of a leaving group (a bromide anion) from the carbon atom: this step is slow. [5] Recombination of carbocation ...

  4. Category:Tert-butyl compounds - Wikipedia

    en.wikipedia.org/wiki/Category:Tert-butyl_compounds

    Tert-Butoxybis(dimethylamino)methane; Butralin; Tert-Butyl alcohol; Tert-Butyl bromide; Tert-Butyl chloride; Tert-Butyl hydroperoxide; Tert-Butyl isocyanide; Butyl PBD; Tert-Butylamine; Butylated hydroxyanisole; Butylated hydroxytoluene; 4-tert-Butylbenzaldehyde; N-tert-Butylbenzenesulfinimidoyl chloride; Para-tert-Butylbenzoic acid; 4-tert ...

  5. Butyl group - Wikipedia

    en.wikipedia.org/wiki/Butyl_group

    The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.

  6. Bulky cyclopentadienyl ligands - Wikipedia

    en.wikipedia.org/wiki/Bulky_cyclopentadienyl_ligands

    Structure of (t Bu 3 C 5 H 2) 2 Fe 2 N 2. The (tert-butyl)cyclopentadiene is prepared by alkylation of cyclopentadiene with tert-butyl bromide in the presence of sodium hydride and dibenzo-18-crown-6. [1] The intermediate in this synthesis is di-tert-butylcyclopentadiene. This compound is conveniently prepared by alkylation of cyclobutadiene ...

  7. Trump readies to name 'fearless' conservative judges in ... - AOL

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    Republican President-elect Donald Trump is poised to build on his legacy of reshaping the federal judiciary with nominees who his allies and opponents predict could be even more conservative than ...

  8. 1,200 readers told us what they regret about investing for ...

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    Gary Lee Hayes, 70, wished he'd been more regimented with his savings and investments.The California resident briefly served in the Navy, got a degree in public administration, and worked in ...

  9. Butyl bromide - Wikipedia

    en.wikipedia.org/wiki/Butyl_bromide

    2-Bromo-2-methylpropane (tert-butyl bromide) Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.