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Nested closed fullerenes have been named bucky onions. Cylindrical fullerenes are also called carbon nanotubes or buckytubes. [1] The bulk solid form of pure or mixed fullerenes is called fullerite. [2] Fullerenes had been predicted for some time, but only after their accidental synthesis in 1985 were they detected in nature [3] [4] and outer ...
For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. [1] By adding a polymerizable group, a fullerene polymer can be obtained. Functionalized fullerenes are divided into two classes: exohedral fullerenes with substituents outside the cage and endohedral fullerenes with trapped molecules inside the ...
Alternatively, endohedral hydrogen fullerenes can be produced by opening and closing a fullerene by organic chemistry methods. A recent example of endohedral fullerenes includes single molecules of water encapsulated in C 60. [10] Noble gas endofullerenes are predicted to exhibit unusual polarizability.
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For example, crystallization of C 60 from benzene solution yields triclinic crystals with the formula C 60 ·4C 6 H 6. Like other solvates, this one readily releases benzene to give the usual face-centred cubic C 60. Millimeter-sized crystals of C 60 and C 70 can be grown from solution both for solvates and for pure fullerenes. [37] [38]
They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways. Fullerene-containing polymers are divided into following structural categories: Intrinsic polymeric fullerene (homopolymer), Main-chain polymers, Side-chain polymers, Star polymers, Crosslinked polymers,
Fullerenes are typically spheroidal carbon compounds, the most prevalent being buckminsterfullerene, C 60. [2] One year after it was prepared in milligram quantities in 1990, [3] C 60 was shown to function as a ligand in the complex [Ph 3 P] 2 Pt(η 2-C 60). [4] Since this report, a variety of transition metals and binding modes were demonstrated.
Fullerenes are a class of carbon allotropes that were first discovered in 1985 and are also an example of macromolecular cages. Buckminsterfullerene (C 60 ) and the 60 atoms of this molecule are arranged in a cage-like structure and the framework resembles a soccer ball; the molecule has an icosahedral symmetry.