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Nitrogen is the most important fertilizer since nitrogen is present in proteins (amide bonds between amino acids), DNA (puric and pyrimidic bases), and other components (e.g., tetrapyrrolic heme in chlorophyll). To be nutritious to plants, nitrogen must be made available in a "fixed" form.
Nitrogen fertilizers and synthetic products, such as urea and ammonium nitrate, are mainstays of industrial agriculture, and are essential to the nourishment of at least two billion people. [10] [13] Industrial facilities using the Haber process and its analogues have a significant ecological impact. Half of the nitrogen in the great quantities ...
In France, Jean Baptiste Boussingault (1802–1887) pointed out that the amount of nitrogen in various kinds of fertilizers is important. Metallurgists Percy Gilchrist (1851–1935) and Sidney Gilchrist Thomas (1850–1885) invented the Gilchrist–Thomas process, which enabled the use of high phosphorus acidic Continental ores for steelmaking.
Fertilizer production is now the largest source of human-produced fixed nitrogen in the terrestrial ecosystem. Ammonia is a required precursor to fertilizers , explosives , and other products. The Haber process requires high pressures (around 200 atm) and high temperatures (at least 400 °C), which are routine conditions for industrial catalysis.
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
Even though nitrogen is a necessary element for life, too much of it in water can have negative effects on aquatic ecosystems and endanger human health. Agricultural runoff, where fertilizers containing nitrogen compounds can seep into rivers, lakes, and groundwater, is one of the main sources of nitrogen in water.
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