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In 1802 the term "metalloids" was introduced for elements with the physical properties of metals but the chemical properties of non-metals. [194] However, in 1811, the Swedish chemist Berzelius used the term "metalloids" [195] to describe all nonmetallic elements, noting their ability to form negatively charged ions with oxygen in aqueous ...
These definitions are equivalent to stating that metals conduct electricity at absolute zero, as suggested by Nevill Francis Mott, [2]: 257 and the equivalent definition at other temperatures is also commonly used as in textbooks such as Chemistry of the Non-Metals by Ralf Steudel [3] and work on metal–insulator transitions. [4] [5]
Metals are said to be fusible, resulting in some confusion in old chemistry as to whether arsenic was a true metal, or a nonmetal, or something in-between. It sublimes rather than melts at standard atmospheric pressure , like the nonmetals carbon and red phosphorus .
The metal is known as a "metal center" and the substance that coordinates to the center is called a "ligand". However, the center does not need to be a metal, as exemplified by boron trifluoride etherate BF 3 OEt 2 , where the highly Lewis acidic , but non-metallic boron center takes the role of the "metal".
Although most metal oxides are crystalline solids, many non-metal oxides are molecules. Examples of molecular oxides are carbon dioxide and carbon monoxide. All simple oxides of nitrogen are molecular, e.g., NO, N 2 O, NO 2 and N 2 O 4. Phosphorus pentoxide is a more complex molecular oxide with a deceptive name, the real formula being P 4 O 10.
This line has been called the amphoteric line, [2] the metal-nonmetal line, [3] the metalloid line, [4] [5] the semimetal line, [6] or the staircase. [2] [n 1] While it has also been called the Zintl border [8] or the Zintl line [9] [10] these terms instead refer to a vertical line sometimes drawn between groups 13 and 14.
Powell P & Timms PL 1974, The Chemistry of the Non-metals, Chapman & Hall, London, ISBN 978-0-470-69570-8. Twenty-two nonmetals including B, Si, Ge, As and Te. Tin and antimony are shown as being intermediate between metals and nonmetals; they are later shown as either metals or nonmetals. Astatine is counted as a metal.
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.