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Arsenic occurs in nature as one stable isotope, 75 As, and is therefore called a monoisotopic element. [28] As of 2024, at least 32 radioisotopes have also been synthesized, ranging in atomic mass from 64 to 95. [29] [30] The most stable of these is 73 As with a half-life of 80.30 days.
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
The old (but extremely sensitive) Marsh test generates AsH 3 in the presence of arsenic. [4] This procedure, published in 1836 by James Marsh, [18] is based upon treating an As-containing sample of a victim's body (typically the stomach contents) with As-free zinc and dilute sulfuric acid: if the sample contains arsenic, gaseous arsine will ...
The total number of unique species, including distinct ionization states, is indicated in each section header. Most of the molecules detected so far are organic. The only detected inorganic molecule with five or more atoms is SiH 4. [14] Molecules larger than that all have at least one carbon atom, with no N−N or O−O bonds. [14]
Cacodylic acid, central to arsenic chemistry, arises from the methylation of arsenic(III) oxide. (In contrast, the dimethylphosphonic acid is less significant in the corresponding chemistry of phosphorus.) Phenylarsonic acids can be accessed by the reaction of arsenic acid with anilines, the so-called Bechamp reaction.
Arsenic (33 As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75 As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73 As with a half-life of 80 days.
The arsenic (As) cycle is the biogeochemical cycle of natural and anthropogenic exchanges of arsenic terms through the atmosphere, lithosphere, pedosphere, hydrosphere, and biosphere. Although arsenic is naturally abundant in the Earth's crust, long-term exposure and high concentrations of arsenic can be detrimental to human health. [1] [2]
Other reactions of main group compounds with yellow arsenic have been shown to involve units of arsenic with more than four atoms. In reaction with the silylene compound [PhC(NtBu) 2 SiN(SiMe 3) 2], an aggregation of As 4 was observed to form a cage compound of ten arsenic atoms, including a seven-membered arsenic ring at its center. [9]