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Second-order phase transitions are continuous in the first derivative (the order parameter, which is the first derivative of the free energy with respect to the external field, is continuous across the transition) but exhibit discontinuity in a second derivative of the free energy. [6]
Informally, the second derivative can be phrased as "the rate of change of the rate of change"; for example, the second derivative of the position of an object with respect to time is the instantaneous acceleration of the object, or the rate at which the velocity of the object is changing with respect to
Landau theory (also known as Ginzburg–Landau theory, despite the confusing name [1]) in physics is a theory that Lev Landau introduced in an attempt to formulate a general theory of continuous (i.e., second-order) phase transitions. [2]
Second order approximation, an approximation that includes quadratic terms; Second-order arithmetic, an axiomatization allowing quantification of sets of numbers; Second-order differential equation, a differential equation in which the highest derivative is the second; Second-order logic, an extension of predicate logic
An example of second-order conditioning. In classical conditioning, second-order conditioning or higher-order conditioning is a form of learning in which a stimulus is first made meaningful or consequential for an organism through an initial step of learning, and then that stimulus is used as a basis for learning about some new stimulus.
Charge ordering (CO) is a (first- or second-order) phase transition occurring mostly in strongly correlated materials such as transition metal oxides or organic conductors. Due to the strong interaction between electrons, charges are localized on different sites leading to a disproportionation and an ordered superlattice.
Then sentences that were second-order become first-order, with the formerly second-order quantifiers ranging over the second sort instead. This reduction can be attempted in a one-sorted theory by adding unary predicates that tell whether an element is a number or a set, and taking the domain to be the union of the set of real numbers and the ...
where n 2 is the second-order nonlinear refractive index, and I is the intensity of the wave. The refractive index change is thus proportional to the intensity of the light travelling through the medium. The values of n 2 are relatively small for most materials, on the order of 10 −20 m 2 W −1 for typical glasses.