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1,3-Dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb, chemical formula C 3 HF 5 Cl 2) is a hydrochlorofluorocarbon.It is a volatile derivative of propane which has served as an HCFC replacement for the CFC, 1,1,2-trichloro-1,2,2-trifluoroethane which was used as a cleaning agent which has been used in the aerospace and electronics industries [2] since the phase out of class 1 ozone depleting ...
In the stratosphere, CFC-113 can be broken up by ultraviolet radiation (UV, sunlight in the 190-225 nm range), generating chlorine radicals (Cl•), which initiate degradation of ozone requiring only a few minutes: [10] [11] CClF 2 CCl 2 F → C 2 F 3 Cl 2 + Cl• Cl• + O 3 → ClO• + O 2. This reaction is followed by: ClO• + O → Cl ...
2,2-Dichloro-1,1,1-trifluoroethane can be produced by reacting tetrachloroethylene with hydrogen fluoride in the gas phase. This is an exothermic reaction and requires a catalyst: This is an exothermic reaction and requires a catalyst:
Between 2012 and 2017, concentrations of the gas jumped by 40 percent. [5] In 2020, the global mean concentration of CFC-113a was 1.02 parts per trillion with global emissions of 2.5 ± 0.4 ODP-Gg yr −1. [6]
1,2-Dichloro-1,1,2-trifluoroethane is a volatile liquid chlorofluoroalkane composed of carbon, hydrogen, chlorine and fluorine, and with structural formula CClF 2 CHClF. It is also known as a refrigerant with the designation R-123a .
1,2-Dibromotetrachloroethane (DBTCE) is an organohalide with the chemical formula C 2 Br 2 Cl 4. It is a crystalline solid that emits lachrymatory ( tear -producing) vapours. [ 2 ] Dibromotetrachloroethane can be used as a fungicide , [ 2 ] flame retardant [ 3 ] and a source for bromine in the laboratory. [ 4 ]
1,1,1,2-Tetrafluoroethane is a non-flammable gas used primarily as a "high-temperature" refrigerant for domestic refrigeration and automobile air conditioners. These devices began using 1,1,1,2-tetrafluoroethane in the early 1990s as a replacement for the more environmentally harmful R-12. Retrofit kits are available to convert units that were ...
Tetrachloro-1,1-difluoroethane can be prepared in 40% yield by reacting 1,1,2-trichloro-1,2,2-trifluoroethane (freon 113) with aluminium chloride at 60°C. [2] It can also be made in a reaction with hydrogen fluoride with hexachloroethane or tetrachloroethane with extra chlorine. This reaction occurs with an aluminium fluoride catalyst at 400°C.
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