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Biphenyl (also known as diphenyl, phenylbenzene, 1,1′-biphenyl, lemonene [4] or BP) is an organic compound that forms colorless crystals. Particularly in older literature, compounds containing the functional group consisting of biphenyl less one hydrogen (the site at which it is attached) may use the prefixes xenyl or diphenylyl .
Diethyl ether has higher water solubility of 8 g per 100 mL, versus diphenyl ether, with a solubility of 0.002 g per 100 mL. [ 3 ] [ 4 ] The presence of the aromatic ring also draws electrons away from the ethereal oxygen, making the hydrolysis of a phenol ether significantly more difficult than that of an alkyl ether. [ 5 ]
The phenyl group is closely related to benzene and can be viewed as a benzene ring, minus a hydrogen, which may be replaced by some other element or compound to serve as a functional group. A phenyl group has six carbon atoms bonded together in a hexagonal planar ring, five of which are bonded to individual hydrogen atoms, with the remaining ...
Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline.
Also known as diphenylbenzenes or triphenyls, they consist of a central benzene ring substituted with two phenyl groups. There are three substitution patterns: ortho-terphenyl, meta-terphenyl, and para-terphenyl. Commercial grade terphenyl is generally a mixture of the three isomers.
Wittig reactions are most commonly used to convert aldehydes and ketones to alkenes. [1] [2] [3] Most often, the Wittig reaction is used to introduce a methylene group using methylenetriphenylphosphorane (Ph 3 P=CH 2). Using this reagent, even a sterically hindered ketone such as camphor can be converted to its methylene derivative.
If you've been having trouble with any of the connections or words in Sunday's puzzle, you're not alone and these hints should definitely help you out. Plus, I'll reveal the answers further down ...
1,1-Diphenylethylene is technical prepared by alkylating benzene by styrene in presence of a zeolite beta and subsequent dehydrogenation. [6] styrene + benzene → 1,1-diphenylethane → 1,1-diphenylethylene + H 2