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Linear low-density polyethylene (LLDPE) is a substantially linear polymer (polyethylene), with significant numbers of short branches, commonly made by copolymerization of ethylene with longer-chain olefins. Linear low-density polyethylene differs structurally from conventional low-density polyethylene (LDPE) because of the absence of long chain ...
LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
Polyethylene was first synthesized by the German chemist Hans von Pechmann, who prepared it by accident in 1898 while investigating diazomethane. [12] [a] [13] [b] When his colleagues Eugen Bamberger and Friedrich Tschirner characterized the white, waxy substance that he had created, they recognized that it contained long −CH 2 − chains and termed it polymethylene.
Analysis of copolymers typically requires multiple characterization methods. For instance, copolymers with short chain branching such as linear low-density polyethylene (a copolymer of ethylene and a higher alkene such as hexene or octene) require the use of Analytical Temperature Rising Elution Fractionation (ATREF) techniques. These ...
The most common stretch wrap material is linear low-density polyethylene (LLDPE), which is produced by copolymerization of ethylene with alpha-olefins, the most common of which are butene, hexene and octene.
There are a wide range of applications for linear alpha olefins. The lower carbon numbers, 1-butene, 1-hexene and 1-octene are overwhelmingly used as comonomer in production of polyethylene. High-density polyethylene and linear low-density polyethylene use approximately 2-4% and 8-10% of comonomers, respectively.
Polyethylene – The most common plastic film is made of one of the varieties of polyethylene: low-density polyethylene, medium-density polyethylene, high-density polyethylene, or linear low-density polyethylene. Polypropylene – Polypropylene can be made a cast film, biaxially oriented film (BOPP), or as a uniaxially oriented film.
Low-density polyethylene (LDPE) is flexible and is used in the manufacture of squeeze bottles, milk jug caps, retail store bags and linear low-density polyethylene (LLDPE) as stretch wrap in transporting and handling boxes of durable goods, and as the common household food covering.