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Anhydrous aluminium chloride is a powerful Lewis acid, capable of forming Lewis acid-base adducts with even weak Lewis bases such as benzophenone and mesitylene. [14] It forms tetrachloroaluminate ([AlCl 4] −) in the presence of chloride ions. Aluminium chloride reacts with calcium and magnesium hydrides in tetrahydrofuran forming ...
This page was last edited on 28 November 2023, at 03:43 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
Aluminium chlorohydrate is a group of water-soluble, [1] specific aluminium salts having the general formula Al n Cl 3n−m (O H) m.It is used in cosmetics as an antiperspirant and as a coagulant in water purification.
In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process:
A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct.
The Gattermann reaction (also known as the Gattermann formylation and the Gattermann salicylaldehyde synthesis) is a chemical reaction in which aromatic compounds are formylated by a mixture of hydrogen cyanide (HCN) and hydrogen chloride (HCl) in the presence of a Lewis acid catalyst such as aluminium chloride (AlCl 3). [1]
Gold(III) chloride is a diamagnetic light-sensitive red crystalline solid that forms the orange monohydrate, AuCl 3 · H 2 O; the anhydrous and monohydrate are both hygroscopic. The anhydrous form absorbs moisture from the air to form the monohydrate which can be reversed by the addition of thionyl chloride. [5]
Aside from anhydrous AlF 3, several hydrates are known.With the formula AlF 3 ·xH 2 O, these compounds include monohydrate (x = 1), two polymorphs of the trihydrate (x = 3), a hexahydrate (x = 6), and a nonahydrate (x = 9).
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