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The SI unit of molar absorption coefficient is the square metre per mole (m 2 /mol), but in practice, quantities are usually expressed in terms of M −1 ⋅cm −1 or L⋅mol −1 ⋅cm −1 (the latter two units are both equal to 0.1 m 2 /mol).
Variable pathlength absorption spectroscopy uses a determined slope to calculate concentration. As stated above this is a product of the molar absorptivity and the concentration. Since the actual absorbance value is taken at many data points at equal intervals, background subtraction is generally unnecessary.
absorption coefficient is essentially (but not quite always) synonymous with attenuation coefficient; see attenuation coefficient for details; molar absorption coefficient or molar extinction coefficient , also called molar absorptivity , is the attenuation coefficient divided by molarity (and usually multiplied by ln(10), i.e., decadic); see ...
When an isosbestic plot is constructed by the superposition of the absorption spectra of two species (whether by using molar absorptivity for the representation, or by using absorbance and keeping the same molar concentration for both species), the isosbestic point corresponds to a wavelength at which these spectra cross each other.
In the context of ozone shielding of ultraviolet light, absorption cross section is the ability of a molecule to absorb a photon of a particular wavelength and polarization. Analogously, in the context of nuclear engineering, it refers to the probability of a particle (usually a neutron ) being absorbed by a nucleus.
Standard molar entropy, S o solid: 160.7 J/(mol K) [5] Heat capacity, c p: 111.46 J/(mol K) [5] Liquid properties Std enthalpy change of formation, Δ f H o liquid: −277.38 kJ/mol Standard molar entropy, S o liquid: 159.9 J/(mol K) Enthalpy of combustion, Δ c H o: −1370.7 kJ/mol Heat capacity, c p: 112.4 J/(mol K) Gas properties Std ...
The spectrum of pure bilirubin is known, so the molar attenuation coefficient ε is known. Measurements of decadic attenuation coefficient μ 10 are made at one wavelength λ that is nearly unique for bilirubin and at a second wavelength in order to correct for possible interferences.
Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p: 0.212 J/(mol K) at −200°C Liquid properties Std enthalpy change of formation, Δ f H o liquid: −318.2 kJ/mol Standard molar entropy, S o liquid: 180 J/(mol K) Heat capacity, c p: 2.68 J/(gK) at 20°C-25°C Gas properties Std enthalpy change of formation, Δ f H o gas: −261. ...