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In carbohydrate chemistry, a pair of anomers (from Greek ἄνω 'up, above' and μέρος 'part') is a pair of near-identical stereoisomers or diastereomers that differ at only the anomeric carbon, the carbon atom that bears the aldehyde or ketone functional group in the sugar's open-chain form.
An oligosaccharide has both a reducing and a non-reducing end. The reducing end of an oligosaccharide is the monosaccharide residue with hemiacetal functionality, thereby capable of reducing the Tollens’ reagent, while the non-reducing end is the monosaccharide residue in acetal form, thus incapable of reducing the Tollens’ reagent. [2]
The α- and β-anomers of D-glucopyranose.. In organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less-hindered equatorial orientation that would be expected ...
The chair conformation of six-membered rings have a dihedral angle of 60° between adjacent substituents thus usually making it the most stable conformer. Since there are two possible chair conformation steric and stereoelectronic effects such as the anomeric effect, 1,3-diaxial interactions, dipoles and intramolecular hydrogen bonding must be taken into consideration when looking at relative ...
Glucose (C 6 H 12 O 6) is one of the most important carbohydrates; others include fructose (C 6 H 12 O 6), the sugar commonly associated with the sweet taste of fruits, [36] [a] and deoxyribose (C 5 H 10 O 4), a component of DNA. A monosaccharide can switch between acyclic (open-chain) form and a cyclic form.
A carbohydrate is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula C m (H 2 O) n (where m may or may not be different from n), which does not mean the H has covalent bonds with O (for example with CH 2 O, H has a covalent bond with C but not with O).
Carbohydrate synthesis is a sub-field of organic chemistry concerned with generating complex carbohydrate structures from simple units (monosaccharides). The generation of carbohydrate structures usually involves linking monosaccharides or oligosaccharides through glycosidic bonds, a process called glycosylation. Therefore, it is important to ...
Zhenxin Wang and coworker the same principle applied this method to detect the interaction between carbohydrate and protein. Carbohydrate biosensor; As Lectin can strongly bind to specific carbohydrate, scientists develop several lectin-based carbohydrate biosensors. [13] Designed lectin contains specific groups can be detected by analytical ...