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  2. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    A chemical reaction may undergo different reaction mechanisms at different temperatures. [13] In this case, a Van 't Hoff plot with two or more linear fits may be exploited. Each linear fit has a different slope and intercept, which indicates different changes in enthalpy and entropy for each distinct mechanisms.

  3. Standard enthalpy of reaction - Wikipedia

    en.wikipedia.org/wiki/Standard_enthalpy_of_reaction

    The standard enthalpy of reaction (denoted ) for a chemical reaction is the difference between total product and total reactant molar enthalpies, calculated for substances in their standard states. The value can be approximately interpreted in terms of the total of the chemical bond energies for bonds broken and bonds formed.

  4. Thermochemical equation - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_equation

    Enthalpy is the transfer of energy in a reaction (for chemical reactions, it is in the form of heat) and is the change in enthalpy. Δ H {\displaystyle \Delta H} is a state function, meaning that Δ H {\displaystyle \Delta H} is independent of processes occurring between initial and final states.

  5. Table of thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Table_of_thermodynamic...

    Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer

  6. Enthalpy - Wikipedia

    en.wikipedia.org/wiki/Enthalpy

    An enthalpy change describes the change in enthalpy observed in the constituents of a thermodynamic system when undergoing a transformation or chemical reaction. It is the difference between the enthalpy after the process has completed, i.e. the enthalpy of the products assuming that the reaction goes to completion, and the initial enthalpy of ...

  7. Gibbs–Helmholtz equation - Wikipedia

    en.wikipedia.org/wiki/Gibbs–Helmholtz_equation

    This equation quickly enables the calculation of the Gibbs free energy change for a chemical reaction at any temperature T 2 with knowledge of just the standard Gibbs free energy change of formation and the standard enthalpy change of formation for the individual components. Also, using the reaction isotherm equation, [8] that is

  8. Standard enthalpy of formation - Wikipedia

    en.wikipedia.org/wiki/Standard_enthalpy_of_formation

    For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.

  9. Heat equation - Wikipedia

    en.wikipedia.org/wiki/Heat_equation

    A fundamental solution, also called a heat kernel, is a solution of the heat equation corresponding to the initial condition of an initial point source of heat at a known position. These can be used to find a general solution of the heat equation over certain domains; see, for instance, ( Evans 2010 ) for an introductory treatment.