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  2. Transition metal dinitrogen complex - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_di...

    The dinitrogen complex trans-[IrCl(N 2)(PPh 3) 2] is made by treating Vaska's complex with aromatic acyl azides. It has a planar geometry. [7] The first preparation of a metal-dinitrogen complex using dinitrogen was reported in 1967 by Yamamoto and coworkers. They obtained [Co(H)(N 2)(PPh 3) 3] by reduction of Co(acac) 3 with AlEt 2 OEt under ...

  3. Covalent bond - Wikipedia

    en.wikipedia.org/wiki/Covalent_bond

    Bonds with one or three electrons can be found in radical species, which have an odd number of electrons. The simplest example of a 1-electron bond is found in the dihydrogen cation, H + 2. One-electron bonds often have about half the bond energy of a 2-electron bond, and are therefore called "half bonds".

  4. d electron count - Wikipedia

    en.wikipedia.org/wiki/D_electron_count

    The ion is formed by removal of the outer s electrons and tends to have a d n configuration, [3]: 40 even though the s subshell is added to neutral atoms before the d subshell. For example, the Ti 2+ ion has the ground-state configuration [Ar]3d 2 [ 8 ] with a d electron count of 2, even though the total number of electrons is the same as the ...

  5. Valence electron - Wikipedia

    en.wikipedia.org/wiki/Valence_electron

    For example, the electronic configuration of phosphorus (P) is 1s 2 2s 2 2p 6 3s 2 3p 3 so that there are 5 valence electrons (3s 2 3p 3), corresponding to a maximum valence for P of 5 as in the molecule PF 5; this configuration is normally abbreviated to [Ne] 3s 2 3p 3, where [Ne] signifies the core electrons whose configuration is identical ...

  6. Electron shell - Wikipedia

    en.wikipedia.org/wiki/Electron_shell

    In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus.The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.

  7. Nitrogen - Wikipedia

    en.wikipedia.org/wiki/Nitrogen

    It, therefore, has five valence electrons in the 2s and 2p orbitals, three of which (the p-electrons) are unpaired. It has one of the highest electronegativities among the elements (3.04 on the Pauling scale), exceeded only by chlorine (3.16), oxygen (3.44), and fluorine (3.98).

  8. Triple bond - Wikipedia

    en.wikipedia.org/wiki/Triple_bond

    Triple bonding can be explained in terms of orbital hybridization.In the case of acetylene, each carbon atom has two sp-orbitals and two p-orbitals.The two sp-orbitals are linear, with 180° bond angles, and occupy the x-axis in the cartesian coordinate system.

  9. Valence (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Valence_(chemistry)

    The valence is the combining capacity of an atom of a given element, determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1.