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Bis(trifluoromethanesulfonyl)aniline is the organic compound with the formula C 6 H 5 N(SO 2 CF 3) 2. [1] It is a white solid. The compound is used to install the triflyl group (SO 2 CF 3). Its behavior is akin to that of triflic anhydride, but milder.
Triflyl group. In organic chemistry, the triflyl group (systematic name: trifluoromethanesulfonyl group) is a functional group with the formula R−SO 2 CF 3 and structure R−S(=O) 2 −CF 3.
Its pK a value in water cannot be accurately determined but in acetonitrile it has been estimated as −0.10 and in 1,2-dichloroethane −12.3 (relative to the pK a value of 2,4,6-trinitrophenol (picric acid), anchored to zero to crudely approximate the aqueous pK a scale [2]), making it more acidic than triflic acid (pK a MeCN = 0.70, pK a DCE ...
In the selected ion flow tube mass spectrometer, SIFT-MS, ions are generated in a microwave plasma ion source, usually from a mixture of laboratory air and water vapor. . From the formed plasma, a single ionic species is selected using a quadrupole mass filter to act as "precursor ions" (also frequently referred to as primary or reagent ions in SIFT-MS and other processes involving chemical ...
[1] In water tube boilers, the way the water is recirculated inside the boiler before becoming steam can be described as either natural circulation or forced circulation. In a water tube boiler, the water is recirculated inside until the vapor pressure of the water overcomes the vapor pressure inside the stream drum and becomes saturated steam.
The following compounds are liquid at room temperature and are completely miscible with water; ... C 2 H 8 N 2: 1,1-dimethylhydrazine: 57-14-7 C 2 H 8 N 2: 1,2 ...
An early report (1949) describes the photochemical reaction of iodotrifluoromethane with ethylene to 3-iodo-1,1,1-trifluoropropane. [53] Reagents that have been reported for the direct trifluoromethylation of arenes are CF 3 I, CF 3 Br (thermal or photochemical), silver trifluoroacetate /TiO 2 (photochemical) and sodium ...
Because of its very high solubility in water (> 21 m), LiTFSI has been used as lithium salt in water-in-salt electrolytes for aqueous lithium-ion batteries. [4] [5]