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Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN) 6] 4−. In its hydrous form, Na 4 Fe(CN) 6 · H 2 O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ...
Ferrocyanide is the name of the anion [Fe 6] 4−. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K 4 Fe(CN) 6. [Fe(CN) 6] 4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment.
+4 +6 +8 8 [136] 109 meitnerium: Mt +1 +3 +6 9 [136] 110 darmstadtium: Ds +2 +4 +6 10 [136] 111 roentgenium: Rg −1 +3 +5 11 [136] 112 copernicium: Cn +2 +4 12 [136] 113 nihonium: Nh 13 114 flerovium: Fl 14 115 moscovium: Mc 15 116 livermorium: Lv −2 +4 16 [137] 117 tennessine: Ts −1 +5 17 118 oganesson: Og −1 +1 +2 +4 +6 18 [136] [138 ...
Oxidation numbers are fundamental to the chemical nomenclature of ionic compounds. For example, Cu compounds with Cu oxidation state +2 are called cupric and those with state +1 are cuprous. [4]: 172 The oxidation numbers of elements allow predictions of chemical formula and reactions, especially oxidation-reduction reactions. The oxidation ...
2 K 4 [Fe(CN) 6] + Cl 2 → 2 K 3 [Fe(CN) 6] + 2 KCl. This reaction can be used to remove potassium hexacyanidoferrate(II) from a solution. [citation needed] A famous reaction involves treatment with ferric salts, most commonly Iron(III) chloride, to give Prussian blue. In the reaction with Iron(III) chloride, producing Potassium chloride as a ...
Compounds that obey the 18-electron rule are typically "exchange inert". Examples include [Co(NH 3) 6]Cl 3, Mo(CO) 6, and [Fe(CN) 6] 4−.In such cases, in general ligand exchange occurs via dissociative substitution mechanisms, wherein the rate of reaction is determined by the rate of dissociation of a ligand.
Prussian blue (also known as Berlin blue, Brandenburg blue, Parisian and Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula Fe 3+ 4 [Fe 2+ 6] 3.
Na 2 [Fe(CO) 4] + RBr → Na[RFe(CO) 4] + NaBr. This solution is then treated sequentially with PPh 3 and then acetic acid to give the aldehyde, RCHO. Disodium tetracarbonylferrate can be used to convert acyl chlorides to aldehydes. This reaction proceeds via the intermediacy of iron acyl complex. Na 2 [Fe(CO) 4] + RCOCl → Na[RC(O)Fe(CO) 4 ...